#  PublicationsA 

 



**2012**

221\. Cassandra G.F. Siler, Bingjun Xu, Robert J. Madix, C.M. Friend, “[Role of Surface-Bound Intermediates in the Oxygen-Assisted Synthesis of Amides by Metallic Silver and Gold](http://apps.webofknowledge.com.ezp-prod1.hul.harvard.edu/full_record.do?product=WOS&search_mode=GeneralSearch&qid=2&SID=2AG72h3oad@GF7NaLfK&page=1&doc=1)” *J. Am Chem. Soc.* **2012**, 134 (30), 12604-12610 , DOI: 10.1021/ja303178z .  
   
220\. Stephen C. Jensen, Alex Shank, R.J. Madix, and C.M. Friend, “Butyrophenone on O-TiO2(110): One-Dimensional Motion in a Weakly Confined Potential Well”, *ACS Nano* **2012,** 6(4), 2925-2930, **DOI:** 10.1021/nn300949q.

219\. Juan Carlos Rodriguez-Reyes, Cynthia M. Friend, Robert J. Madix, “[Origin of the selectivity in the gold-mediated oxidation of benzyl alcohol](http://apps.webofknowledge.com.ezp-prod1.hul.harvard.edu/full_record.do?product=WOS&search_mode=GeneralSearch&qid=2&SID=2AG72h3oad@GF7NaLfK&page=1&doc=2).” *Surf. Sci*. **2012,** 606 15-16 1129-1134; DOI: 10.1016/j.susc.2012.03.013.

218\. Bingjun Xu, R.J. Madix, and C.M. Friend, “Dual-Function of Alcohols in Gold-Mediated Selective Coupling of Amines and Alcohols”, *Chemistry—A European Journal,* **2012**, 18 (8), 2313-2318, **DOI:**10.1002/chem.201103232.

217\. Kathryn Kosuda, Arne Wittstock, C. M. Friend and Marcus Bäumer, “Oxygen-Mediated Coupling of Alcohols over Nanoporous Gold Catalysts at Ambient Pressures, *Ang. Chemie Int. Ed.* **2011**, 51(7), 1698-1701, **DOI:** 10.1002/anie.201107178.

  
**2011**

216\. Bingjun Xu, R.J. Madix, and C.M. Friend, “Activated Metallic Gold as an Agent for Direct Methoxycarbonylation”, *J. Am. Chem. Soc.*, **2011**, 133 (50), 20378-20383, **DOI:** 10.1021/ja207389z.

215\. R.J. Madix and C.M. Friend, “Interfacial Chemistry Gold’s Enigmatic Surface”, *Nature*, **2011** 479 482-483.

214\. Stephen C. Jensen, Jan Haubrich, Alex Shank, Cynthia M. Friend, et al., “[Carbonyl Coupling: Defects and O2 Make or Break the Essential Reaction Intermediate on Titanium Dioxide”](http://apps.webofknowledge.com/full_record.do?product=WOS&search_mode=GeneralSearch&qid=2&SID=4EoDkp1PKMF9dEHJC4N&page=1&doc=1&cacheurlFromRightClick=no), *Chemistry-A European Journal,* **2011**, 17 (30), 8309-8312, **DOI**: 10.1002/chem.201101094.  
   
213\. Bingjun Xu, Cynthia M. Friend, Robert J. Madix, “[A paradigm for predicting selective oxidation on noble metals: oxidative catalytic coupling of amines and aldehydes on metallic gold”, ](http://apps.webofknowledge.com/full_record.do?product=WOS&search_mode=GeneralSearch&qid=2&SID=4EoDkp1PKMF9dEHJC4N&page=1&doc=6) *Faraday Discussions*, **2011**, 152, 241-252, **DOI**: 10.1039/c1fd00012h.

212\. Bingjun Xu, Cynthia M. Friend, “[Oxidative coupling of alcohols on gold: Insights from experiments and theory” ](http://apps.webofknowledge.com/full_record.do?product=WOS&search_mode=GeneralSearch&qid=2&SID=4EoDkp1PKMF9dEHJC4N&page=1&doc=7) *Faraday Discussions*, **2011**, 152, 307-320 **DOI**: 10.1039/c1fd00015b.  
   
211\. Thomas A. Baker, Bingjun Xu, Stephen C. Jensen, Cynthia M. Friend, et al.  
 “[Role of defects in propene adsorption and reaction on a partially O-covered Au(111) surface”, ](http://apps.webofknowledge.com/full_record.do?product=WOS&search_mode=GeneralSearch&qid=2&SID=4EoDkp1PKMF9dEHJC4N&page=1&doc=9)*Catalysis Science & Technology*, **2011**, 1 (7) 1166-1174 **DOI:** 10.1039/c1cy00076d.

210\. Jan Haubrich, Efthimios Kaxiras, Cynthia M. Friend, “The role of surface and subsurface point defects for chemical model studies on TiO2(110)…”, *Chem.—A European Journal*, 117, 4496-4506 **2011**, **DOI:** 10.1002/chem.201002588

209\. Bingjun Xu, Efthimios Kaxiras, Cynthia M. Friend, “Theoretical Study of O-assisted coupling of methanol on Au(111), *J. Phys. Chem*. C, **2011**, 115 (9) 3703-3708; DOI: 10.1021/jp110835w.

208\. Lauren Benz, Jan Haubrich, Stephen C. Jensen, Cynthia M. Friend, “Molecular Imaging of Reductive Coupling Reactions: Interstitial-mediated Coupling of Benzaldehyde on TiO2(110)”, *ACS Nano*, **2011**. (**DOI:** 10.1021/nn103144u.)

207\. Thomas A. Baker, Xiaoying Liu, and C.M. Friend, “The Mystery Of Gold’s Chemical Activity: Local Bonding, Morphology And Reactivity Of Atomic Oxygen”, *Physical Chemistry-Chemical Physics* (Invited Perspective Article; Selected for inside cover art), **2011**, 13, 34-46. (DOI: 10.1039/C0CP01514H).

  
**2010**

206\. Bingjun [Xu](http://apps.isiknowledge.com.ezp-prod1.hul.harvard.edu/DaisyOneClickSearch.do?product=WOS&search_mode=DaisyOneClickSearch&db_id=&SID=2FfK1JKCKOPCfpnaDiL&name=Xu%20BJ&ut=000284792000048&pos=1), R.J. [Madix, and C.M. Friend,](http://apps.isiknowledge.com.ezp-prod1.hul.harvard.edu/DaisyOneClickSearch.do?product=WOS&search_mode=DaisyOneClickSearch&db_id=&SID=2FfK1JKCKOPCfpnaDiL&name=Madix%20RJ&ut=000284792000048&pos=2) “Achieving Optimum Selectivity in Oxygen Assisted Alcohol Cross-Coupling on Gold”, *J. Am. Chem. Soc*. 2010, 132, 16571-16580. (DOI: 10.1021/ja106706v)

205\. Xiaoying Liu, Thomas A. Baker, and C.M. Friend, “Effect of Molecular Structure on the Epoxidaiton of Allylic Olefins by Atomic Oxygen on Au.” *Dalton Trans*. 2010, 39 8521-8526, DOI: 10.1039/C0DT00047G.

204\. Bingjun Xu, Jan Haubrich, Cassandra G. Freyschlag, Robert J. Madix and Cynthia M. Friend. ”Oxygen-assisted cross-coupling of methanol with alkyl alcohols on metallic gold”, *Chem. Sci*., 2010, 1, 310-314, DOI: 10.1039/C0SC00214C. (Selected for cover of journal.)

203\. Xiaoying Liu and C.M. Friend, “Selective Oxidation of Cyclohexanol and 2-Cyclohexen-1-ol on O/Au(111): The Effect of Molecular Structure”, *Langmuir*, 2010, 16552-16557. DOI: 10.1021/la1015302.

202\. Thomas A. Baker, Efthimios Kaxiras, C.M. Friend, “[Insights from Theory on the Relationship Between Surface Reactivity and Gold Atom Release](http://apps.isiknowledge.com.ezp-prod1.hul.harvard.edu/InboundService.do?SID=1FlH65BEgj87mnka7Fb&uml_return_url=http://pcs.isiknowledge.com/uml/uml_view.cgi?product_sid=1FlH65BEgj87mnka7Fb&product=WOS&marklist_id=WOS&database_id=GB&product_st_thomas=http%3A%2F%2Festi%2Eisiknowledge%2Ecom%3A8360%2Festi%2Fxrpc&sort_opt=Date&action=retrieve&product=WOS&mode=FullRecord&viewType=fullRecord&frmUML=1&UT=000276979100008)”, *Top. Cat*., **2010,** 53 (5-6): 365-377. (DOI: 10.1007/s11244-010-9446-3)

201\. J.A. Haubrich, Ryan G. Quiller, Lauren Benz, L, Z. Liu, and C.M. Friend, “[In Situ Ambient Pressure Studies of the Chemistry of NO2 and Water on Rutile TiO2(110)](http://apps.isiknowledge.com.ezp-prod1.hul.harvard.edu/InboundService.do?SID=1FlH65BEgj87mnka7Fb&uml_return_url=http://pcs.isiknowledge.com/uml/uml_view.cgi?product_sid=1FlH65BEgj87mnka7Fb&product=WOS&marklist_id=WOS&database_id=GB&product_st_thomas=http%3A%2F%2Festi%2Eisiknowledge%2Ecom%3A8360%2Festi%2Fxrpc&sort_opt=Date&action=retrieve&product=WOS&mode=FullRecord&viewType=fullRecord&frmUML=1&UT=000274342200041)”, *Langmuir*, **2010,** 26 (4): 2445-2451. (**DOI:** 10.1021/la904141k).

200\. X. Liu, C.M. Friend, “Competing Epoxidation and Allylic Hydrogen Activation: trans-β-Methylstyrene Oxidation on Au(111),” *J. Phys. Chem. C*, **2010**, 26(4) 2445-2451. (DOI: 10.1021/jp9121529)

199\. A. Wittstock, V. Zielasek, J. Biener, C. M. Friend, and M. Bäumer, “Nanoporous gold catalysts for selective gas-phase oxidative coupling of methanol at low temperature,” *Science*, **2010**, *327*, 319-322. (**DOI:** 10.1126/science.1183591)

198\. B. Xu, L. Zhou, R. J. Madix, and C. M. Friend, “Highly selective acylation of dimethylamine mediated by oxygen atoms on metallic gold surfaces,” *Angew. Chem. Int. Ed*., **2010**, *49*, 394-398. (**DOI:** 10.1002/anie.200905642.)

197\. R. G. Quiller, X. Liu, and C. M. Friend, “Mechanistic insights into selectivity control for heterogeneous olefin oxidation: Styrene oxidation on Au(111),” *Chemistry—An Asian Journal*, **2010**, *5,* 78-86. (**DOI:** 10.1002/asia.200900399.)

196\. L. Zhou, C. G. Freyschlag, B. Xu, C. M. Friend, and R. J. Madix, “[Direct selective oxygen-assisted acylation of amines driven by metallic silver surfaces: dimethylamine with formaldehyde ](https://scifinder.cas.org/scifinder/view/text/refList.jsf?nav=rO0ABXQAAWF0ACQ4RjlDQjM1My04NkYzLTUwOTQtNzIwNC0wMjYzODUwRjc4RkR0AAFic3IAEWphdmEubGFuZy5JbnRlZ2VyEuKgpPeBhzgCAAFJAAV2YWx1ZXhyABBqYXZhLmxhbmcuTnVtYmVyhqyVHQuU4IsCAAB4cAAAAAN0AAFodAAbQVVUSE9SX0lOVkVOVE9SX05PX0dST1VQSU5HdAABcHNxAH4AAwAAAAF0AAJyb3NyABFqYXZhLmxhbmcuQm9vbGVhbs0gcoDVnPruAgABWgAFdmFsdWV4cAB0AAJzc3NyACtvcmcuY2FzLm9zY2FyLnNlcnZlci5kb21haW4uY29tbW9uLlNvcnRTcGVjPJCroB2X4MoCAAJMAAxteU9yZGluYWxLZXl0AChMb3JnL2Nhcy9vc2Nhci9zZXJ2ZXIvZG9tYWluL2NvbW),” *Chem. Comm*. **2010**, *46*, 704-706. (DOI: 10.1039/b921066k.)

195\. T. A. Baker, C. M. Friend, and E. Kaxiras, “Local bonding effects in the oxidation of CO on oxygen-covered Au(111) from ab initio molecular dynamics simulations,” *J. Chem. Theor. Comput.*, **2010**, *6*, 279-287.  
(**DOI:** 10.1021/ct9004596.)

194\. B. Xu, X. Liu, J. Haubrich, and C. M. Friend, “Vapour-phase gold-surface-mediated coupling of aldehydes with methanol,” *Nature Chem*., **2010**, *2*, 61-65. (**DOI:** 10.1038/NCHEM.467.)

  
**2009**

193\. L. Benz, J. Haubrich, R. G. Quiller, S. C. Jensen, and C. M. Friend, "McMurry chemistry on TiO2(110): Reductive C=C coupling of benzldehyde driven by titanium interstitials,” *J. Am. Chem. Soc.*, **2009**, *131*, 15026–15031.

192\. B. K. Min, X. Deng, X. Liu, C. M. Friend, and A. R. Alemozafar, “[Tuning reactivity and selectivity for olefin oxidation through local O bonding on Au ](https://scifinder.cas.org/scifinder/view/text/refList.jsf?nav=rO0ABXQAAWF0ACQxNjQyMDFFRS04NkYzLTUwQjAtNTZEMy0yRjY5M0MyNUNGMjR0AAFic3IAEWphdmEubGFuZy5JbnRlZ2VyEuKgpPeBhzgCAAFJAAV2YWx1ZXhyABBqYXZhLmxhbmcuTnVtYmVyhqyVHQuU4IsCAAB4cAAAAAN0AAFodABAMTY0MjAxRUUtODZGMy01MEIwLTU2RDMtMkY2OTNDMjVDRjI0OkFVVEhPUl9JTlZFTlRPUl9OT19HUk9VUElOR3QAAXBzcQB-AAMAAAABdAACcm9zcgARamF2YS5sYW5nLkJvb2xlYW7NIHKA1Zz67gIAAVoABXZhbHVleHAAdAACc3NzcgArb3JnLmNhcy5vc2Nhci5zZXJ2ZXIuZG9tYWluLmNvbW1vbi5Tb3J0U3BlYzyQq6Adl-DKAgACTAAMbXlPcmRpbmFsS2),” *Chem. Cat. Chem*., **2009**, *1*, 116-121.

191\. T. A. Baker, B. Xu, X. Liu, E. Kaxiras, and C. M. Friend, “[Nature of oxidation of the Au(111) surface. Experimental and theoretical investigation ](https://scifinder.cas.org/scifinder/view/text/refList.jsf?nav=rO0ABXQAAWF0ACQxNjQyMDFFRS04NkYzLTUwQjAtNTZEMy0yRjY5M0MyNUNGMjR0AAFic3IAEWphdmEubGFuZy5JbnRlZ2VyEuKgpPeBhzgCAAFJAAV2YWx1ZXhyABBqYXZhLmxhbmcuTnVtYmVyhqyVHQuU4IsCAAB4cAAAAAN0AAFodABAMTY0MjAxRUUtODZGMy01MEIwLTU2RDMtMkY2OTNDMjVDRjI0OkFVVEhPUl9JTlZFTlRPUl9OT19HUk9VUElOR3QAAXBzcQB-AAMAAAABdAACcm9zcgARamF2YS5sYW5nLkJvb2xlYW7NIHKA1Zz67gIAAVoABXZhbHVleHAAdAACc3NzcgArb3JnLmNhcy5vc2Nhci5zZXJ2ZXIuZG9tYWluLmNvbW1vbi5Tb3J0U3BlYzyQq6Adl-DKAgACTAAMbXlPcmRpbmFsS2).” *J. Phys. Chem. C.,* **2009**, *113*, 16561-16564.

190\. V. Zielasek, B. Xu, X. Liu, M. Bäumer and C. M. Friend, “The Absence of Subsurface Oxygen Effects in the Oxidation of Olefins on Au: Styrene Oxidation over Sputtered Au(111).” *J. Phys. Chem. C,* **2009**, *113*, 8924-8929.

189\. X. Liu, B. Xu, J. Haubrich, R. Madix, and C. M. Friend, “Surface-mediated self-coupling of ethanol on gold.” *J. Am. Chem. Soc.*, **2009**, *131*, 5757-5759.

188\. L. Benz, J. Haubrich, R. G. Quiller, and C. M. Friend, "Acrolein coupling on reduced TiO2(110): The effect of surface oxidation and the role of subsurface defects." *Surf. Sci,* **2009,** *603*, 1010-1017.

187\. R. G. Quiller, L. Benz, J. Haubrich, M. E. Colling, and C. M. Friend, "Surface Chemistry of Organic Pollutants: Styrene, Ozone, and Water on TiO2(110)." *J. Phys. Chem. B.,* **2009,** *113*, 2063-2070.

186\. T. A. Baker, C. M. Friend, and E. Kaxiras, “Atomic Oxygen Adsorption on Au(111) with Defects.” *J. Phys. Chem. C.,* **2009**, *113*, 3232-3238.

185\. B. Xu, X. Liu, J. Haubrich, R. J. Madix, and C. M. Friend, “Selectivity Control in Gold-Mediated Esterification of Methanol.” *Angew. Chem., Int. Ed.*, **2009**, *48*, 4206-4209.

184\. T. A. Baker, C. M. Friend, and E. Kaxiras, “Effects of chlorine and oxygen coverage on the structure of the Au(111) Surface.” *J. Chem. Phys.* **2009**, 130, Art. No. 084701.

  
**2008**

183\. X. Liu, R. J. Madix, and C. M Friend, “Unraveling molecular transformations on surfaces: a critical comparison of oxidation reactions on coinage metals.” *Chemical Society Reviews* **2008**, 37(10), 2243-2261.

182\. R. J. Madix, C. M. Friend, and X. Liu, “Anticipating Catalytic Oxidation Reactions on Gold at High Pressure (Including Liquid Phase) From Ultrahigh Vacuum Studies.”  *J. Catalysis.* **2008**, *258* (2), 410-413.

181\. T. A. Baker, C. M. Friend, and E. Kaxiras, “Chlorine Interaction with Defects on the Au(111) Surface: a First-Principles Theoretical Investigation.” *J. Chem. Phys.* **2008**, *129*, 104702.

180\. R. G. Quiller, T. A. Baker, X. Deng, M. E. Colling, B. K. Min, and C. M. Friend, **“**Transient Hydroxyl Formation from Water on Oxygen-covered Au(111).“ *J. Chem. Phys.* **2008**, *129* 064702.

179\. X. Deng, S. Y. Quek, M. M. Biener, J. Biener, D.-H. Kang, R. Schalek, E. Kaxiras, and C. M. Friend, **“**Selective Thermal Reduction of Single-Layer MoO3 Nanostructures on Au(111).“ *Surf. Sci.* **2008**, *602*(6), 1166-1174.

178\. T. A. Baker, C. M. Friend, and E. Kaxiras, “The Nature of Cl Bonding on the Au(111) Surface: Evidence of a Mainly Covalent Interaction.” *J. Am. Chem. Soc.* **2008,** *130*(12), 3720-3721.  
   
177\. X. Deng and C. M. Friend, **“**Selectivity Switch for Nitrogen Functionalization of Styrene on Au(111).“ *Surf. Sci.* **2008**, *602*(5), 1066-1071.

176\. W. Gao, T. A. Baker, L. Zhou, D. S. Pinnaduwage, E. Kaxiras, and C. M. Friend, “Chlorine Adsorption on Au(111): Chlorine Overlayer or Surface Chloride?” *J. Am. Chem. Soc*. **2008**, *130*(11), 3560-3565.

  
**2007**

175\. S. Y. Quek, M. M. Biener, J. Biener, J. Bhattacharjee, C. M. Friend, U. V. Waghmare, and E. Kaxiras, **“**Structure of incommensurate gold sulfide monolayer on Au(111).” *J. Chem. Phys.* **2007**, *127*(10), 104704/1-104704/8.

174\. W. Gao, L. Zhou, D. S. Pinnaduwage, and C. M. Friend, ”Interaction of Chlorine with Au-O Surface Complexes.” *J. Phys. Chem. C,* **2007**, *111*(26), 9005-9007.

173\. B. K. Min and C. M. Friend, “Heterogeneous Gold-Based Catalysis for Green Chemistry: Low-Temperature CO Oxidation and Propene Oxidation.” *Chem. Rev.,* **2007**, *107*(6), 2709-2724.

172\. S. H. Wiedemann, D.-H. Kang, R. G. Bergman, and C. M. Friend, “Cyclopropylmethyl/Cyclobutyl Rearrangements on Surfaces: Evidence for Transient Cation Formation near O-Covered Mo(110).**”** *J. Am. Chem. Soc.* **2007**, *129*(15), 4666-4677.

171\. M. M. Biener, J. Biener, and C. M. Friend, “Sulfur-Induced Mobilization of Au Surface Atoms on Au(111) Studied by Real-Time STM.” *Surf. Sci.,* **2007**, *601*(7), 1659-1667.

170\. M. A. Sheehy, B. R. Tull, C. M. Friend, and E. Mazur, “Chalcogen Doping of Silicon via Intense Femtosecond-Laser Irradiation.” *Mat. Sci. Eng. B,* **2007**, *137*(1-3), 289-294.

169\. X. Liu, A. Klust, R. J. Madix, and C. M. Friend, “Structure Sensitivity in the Partial Oxidation of Styrene, Styrene Oxide, and Phenylacetaldehyde on Silver Single Crystals.” *J. Phys. Chem. C,* **2007**, *111*(9), 3675-3679.

168\. D. S. Pinnaduwage, L. Zhou, W. Gao and C. M. Friend, “Chlorine Promotion of Styrene Epoxidation on Au(111).” *J. Am Chem. Soc*. **2007**, *129*(7), 1872-1873.

167\. X. V. Zhang, S. P. Ellery, C. M. Friend, H. D. Holland, F. M. Michel, Martin A. A. Schoonen and S. T. Martin, “Photodriven Reduction and Oxidation Reactions on Colloidal Semiconductor Particles: Implications for Prebiotic Synthesis.” *J. Photochem. Photobiol. A* **2007**, *185*(2-3), 301-311.

  
**2006**

166\. X. Deng, T. A. Baker, and C. M. Friend, “A Pathway for NH Addition to Styrene Promoted by Gold.” *Angew. Chem. Int*. *Ed. Engl*. **2006,** *45*(42), 7075-7078.

165\. X. Liu, R. J. Madix, and C. M. Friend, “Surface-Mediated NH and N Addition to Styrene on Ag(110).” *J. Am. Chem Soc.* **2006,** *128*(44), 14266-14267.

164\. J. Biener, M. M. Biener, T. Nowitzki, A. V. Hamza, C. M. Friend, V. Zielasek, and M. Bäumer, “On the Role of Oxygen in Stabilizing Low-Coordinated Au Atoms.” *ChemPhysChem.,* **2006**, *7*(9), 1906-1908.

163\. S. Y. Quek, C. M. Friend, and E. Kaxiras, “Active Role of Buried Ultrathin Oxide Layers in Adsorption of O2 on Au Films.” *Surf. Sci.* **2006**, *600*(17), 3388-3393.

162\. S. Y. Quek, M. M. Biener, J. Biener, J. Bhattacharjee, C. M. Friend, U. V. Waghmare, and E. Kaxiras, “Rich Coordination Chemistry of Au Adatoms in Gold Sulfide Monolayer on Au(111).” *J. Phys. Chem B*  **2006**, *110*(32), 15663-15665.

161\. X. Deng, B. K. Min, X. Liu, and C. M. Friend, “Partial Oxidation of Propene on Oxygen-Covered Au(111).” *J. Phys. Chem B* **2006**, *110*(32), 15982-15987.

160\. B. K. Min, A. R. Alemozafar, D. Pinnaduwage, X. Deng, and C. M. Friend, “Efficient CO Oxidation at Low Temperature on Au(111).” *J. Phys Chem B* **2006,** *110*(40), 19833-19838.

159\. B. R. Tull, J. E. Carey, M. A. Sheehy, C. M. Friend, and E. Mazur, “Formation of Silicon Nanoparticles and Web-like Aggregates by Femtosecond Laser Ablation in a Background Gas.” *Appl. Phys. A* **2006**, *83*(3), 341-346.

  
**2005**

158\. M. M. Biener, J. Biener, and C. M. Friend, “Novel Synthesis of Two-Dimensional TiS2 Nanocrystallites on Au(111).” *J. Chem. Phys.* **2005**, *122*(3), 034706/1-034706/6.  
  
157\. Y.-S. Jun, T. A. Kendall, S. T. Martin, C. M. Friend, and J. J. Vlassak, “Heteroepitaxial Nucleation and Oriented Growth of Manganese Oxide Islands on Carbonate Minerals under Aqueous Conditions.” *Env. Sci. Tech.* **2005**, *39*(5), 1239-1249.  
  
156\. M. M. Biener, J. Biener, and C. M. Friend, “Revisiting the S-Au(111) Interaction: Static or Dynamic?” *Langmuir* **2005**, *21*(5), 1668-1671.  
  
155\. S. Y. Quek, M. M. Biener, J. Biener, C. M. Friend, and E. Kaxiras, “Tuning Electronic Properties of Novel Metal Oxide Nanocrystals Using Interface Interactions: MoO3 Monolayers on Au(111).” *Surf. Sci.* **2005**, *577*(2-3), L71-L77.  
  
154\. L. J. Deiner, D.-H. Kang, and C. M. Friend, “Low-Temperature Reduction of NO2 on Oxidized Mo(110).” *J. Phys. Chem.* **2005**, *109*(26), 12826-12831.  
  
153\. M. M. Biener, J. Biener, R. Schalek, and C. M. Friend, “Surface Alloying of Immiscible Metals: Mo on Au(111) studied by STM.” *Surf. Sci.* **2005,** *594*(1-3), 221-230.  
  
152\. M. M. Biener, J. Biener, and C. M. Friend, “Enhanced Transient Reactivity of an O-Sputtered Au(111) Surface.” *Surf. Sci.* **2005**, *590*(2-3), L259-L265.  
  
151\. M. A. Sheehy, L. Winston, J. E. Carey, C. M. Friend, and E. Mazur, “Role of the Background Gas in the Morphology and Optical Properties of Laser-Microstructured Silicon.” *Chem. Mater.* **2005**, *17*(14), 3582-3586.  
  
150\. J. Biener, E. Farfan-Arribas, M. Biener, C. M. Friend, and R. J. Madix, “Synthesis of TiO2 Nanoparticles on the Au(111) Surface.” *J. Chem. Phys*. **2005,** *123*(9), 094705/1-094705/6*.*  
  
149\. E. Farfan-Arribas, J. Biener, C. M. Friend, and R. J. Madix, “Reactivity of Methanol on TiO2 Nanoparticles Supported on the Au(111) Surface.” *Surf. Sci.* **2005,** *591*(1-3), 1-12.  
  
148\. B. K. Min, X. Deng, D. Pinniduwage, R. Schalek, and C. M. Friend, “Oxygen-Induced Restructuring with Release of Gold Atoms from Au(111).” *Phys Rev. B,* **2005,** *72*(12), 121410/1-121410/4*.*  
  
147**.** B. K. Min, R. G. Quiller, L. J. Deiner, and C. M. Friend, “Water Dissociation Associated with NO2 Coadsorption on Mo(110)-(1x6)-O: Effect of Coverage and Electronic Properties of Oxygen.” *J. Phys. Chem. B* **2005**, *109*(43), 20463-20468.   
  
146\. X. Deng, B. K. Min, A. Guloy, and C. M. Friend, “Enhancement of O2 Dissociation on Au(111) by Adsorbed Oxygen: Implications for Oxidation Catalysis.” *J. Am. Chem. Soc.* **2005**, *127*(25), 9267-9270.  
  
145\. B. K. Min, A .R. Alemozafar, M. M. Biener, J. Biener, and C. M. Friend, “Reaction of Au(111) with Sulfur and Oxygen: Scanning Tunneling Microscopic Study.” *Topics in Catalysis* **2005**, *36*(1-4), 77-90.  
  
144\. X. Deng and C. M. Friend, “Selective Oxidation of Styrene on an Oxygen-Covered Au(111).” *J. Am. Chem. Soc.* **2005,** *127*(49), 17178-17179.  
  
143\. L.J. Deiner, D.-H. Kang, and C.M. Friend ˝Promotion of Formaldehyde Production by oxidation of Mo(110) by NO2.” J. Phys. Chem. B., **2005,**109 (16), 8085-8090.

  
**2004**

142\. B. Flemmig, I. Kretzschmar, C. M. Friend, and Roald Hoffman, “The Cyclopropylmethyl-3-butenyl Rearrangement on Mo(110): A Radical Clock on a Surface?” *J. Phys. Chem. A,* **2004,** *108*(15), 2972-2981**.**  
  
141\. L. J. Deiner, A. S. Y. Chan, M. A. Sheehy, and C. M. Friend, “The Reaction of CH3NO2 on O-covered Mo(110): The Effect of Oxygen on Product Distribution.” S*urf. Sci.* **2004,** *555*(1-3), L127-L132**.**  
  
140\. M. M. Biener and C. M. Friend, “Heteroepitaxial Growth of Novel MoO3 Nanostructures on Au(111).” *Surf. Sci.* **2004,** *559*(2-3), L173-L179**.**  
  
139\. X. V. Zhang, S. T. Martin, C. M. Friend, M. A. A. Schoonen, and H. D. Holland, “Mineral-Assisted Pathways in Prebiotic Synthesis: Photoelectrochemical Reduction of Carbon(+IV) by Manganese Sulfide.” *J. Am. Chem. Soc.* **2004,** *126*(36), 11247-11253.  
  
138\. M. M. Biener, J. Biener, R. Schalek, and C. M. Friend, “Growth of Nanocrystalline MoO3 on Au(111) studied by *in-situ* STM.” *J. Chem. Phys.* **2004**, *121*(23), 12010-12016.   
  
137\. D.-H. Kang and C.M. Friend, “Sensitivity of Methylthiolate Desulfurization Selectivity to Reaction Temperature and Hydroxyl Coverage.” *Langmuir* **2004**, *20*(26), 11443-11449.

  
**2003**

136\. Z. Song, T. Cai, J. A. Rodrigues, J. Hrbek, A. S. Y. Chan, and C. M. Friend, “A Novel Growth Mode of Mo on Au(111) from a Mo(CO)6 Precursor: An STM Study.” *J. Phys. Chem. B* **2003,***107*(4), 1036-1043.  
  
135\. R. Younkin, J. E. Carey, J. A. Levinson, and C. M. Friend, “Infrared Absorption by Conical Silicon Microstructures Made in a Variety of Background Gases using Femtosecond-Laser Pulses.” *J. Appl. Phys*. **2003**, *93*(5), 2626-2629.   
  
134\. M. Y. Shen, C. H. Crouch, J. E. Carey, R. Younkin, E. Mazur, M. Sheehy, and C. M. Friend, “Formation of Regular Arrays of Silicon Microspikes by Femtosecond Laser Irradiation through a Mask.” *Appl. Phys. Lett*. **2003**, *82*, 1715-1717.  
  
133\. I. N. Remediakis, E. Kaxiras, M. Chen, and C. M. Friend, “Dinitrosyl Formation as an Intermediate Stage of the Reduction of NO in the Presence of MoO3.” *J. Chem. Phys.* **2003,** *118*(13), 6046-6051.  
  
132\. L. J. Deiner and C. M. Friend, “Modification of Dehydrogenation Activity of Nickel on O-covered Mo(110).” *Surf. Sci.* **2003**, *539*(1), 21-30.  
  
131\. L. J. Deiner, J. G. Serafin, C. M. Friend, S. G. Weller, J. A. Levinson, and R. E. Palmer, “Insight into the Partial Oxidation of Propene: The Reactions of 2-Propen-1-ol on Clean and O-Covered Mo(110).” *J. Am. Chem. Soc.* **2003**, *125*(43), 13252-13257.

  
**2002**

130\. I. Kretzschmar and C. M. Friend, “Effect of Coadsorbed Species and Temperature on Competitive Reaction Channels for Nascent Radicals: *c*-C3H7CH2SH on Mo(110)-(6x1)-O.” *J. Phys. Chem***.** B **2002,** *106*(3), 663-672.  
  
129\. I. Kretzschmar and C. M. Friend, “Kinetic Control of Surface Reactions: Regioselectivity in the Reaction of 2-Methylcyclopropanemethanol on Mo(110)-(6x1)-O.” *J. Phys. Chem***.** *B,* **2002,** *106* (33), 8407-8414.  
  
128\. A. S. Y. Chan, L. J. Deiner, and C. M. Friend, “Insight into the Catalytic Reduction of NO by Methane: The Reaction of Nitromethane on Oxidized Mo(110).” *J. Phys. Chem. B* **2002,** *106*(51), 13318-13325.

  
**2001**

127\. M. Chen, C. M. Friend, and E. Kaxiras, “The Chemical Nature of Surface Point Defects on MoO3(010): Adsorption of Hydrogen and Methyl." *J. Am. Chem. Soc***. 2001**, *123*(10), 2224-2230.  
  
126\. F. C. Nart and C. M. Friend, “Facile Reduction of NO via Dinitrosyl on Highly Oxidized Mo(110): Sensitivity to Local Structure and Defects.” *J. Phys. Chem***.** *B* **2001**, *105*(14), 2773-2778**.**  
  
125\. L. J. Deiner, S. L. Wilcke, C. M. Friend, and F. C. Nart, “Potential Intermediate in CH4–Assisted Reduction of Nitric Oxide: The Reactions of Methyl Nitrite on Oxidized Mo(110).” *Surf. Sci.* **2001**, *477*, L301-L307.  
  
124\. J. A. Levinson, I. Kretzschmar, M. A. Sheehy, L. J. Deiner, and C. M. Friend, “Rearrangement as a Probe for Radical Formation: Bromomethylcyclopropane on Oxygen-Covered Mo(110)." *Surf. Sci***. 2001**, *479*, 273-286**.**

  
**2000**

123\. M. Chen, C. M. Friend, and E. Kaxiras, “A Density Functional Theory Study of Site-specific Methyl Reaction on MoO3(010): The Effects of Methyl Coverage." *J. Chem. Phys***. 2000**, *112*, 9617-9623**.**  
  
122\. K. T. Queeney and C. M. Friend, “Site-Selective Surface Reactions: Hydrocarbon Oxidation Processes on Oxidized Mo(110).” *J. Phys. Chem***. 2000**, *104*, 409-415.  
  
121\. F. C. Nart, S. Kelling and C. M. Friend, “Oxygen Lability on Thin Oxide Films on Mo(110).” *J. Phys. Chem***.** *B,* **2000**, *104*, 3212-3218**.**  
  
120\. K. T. Queeney and C. M. Friend, “Site-Selective Surface Reactions: Nitric Oxide Reduction on Mo(110).” *ChemPhysChem* **2000**, *1*, 116 – 125.  
  
119\. I. Kretzschmar, J. A. Levinson and C. M. Friend, “Hydroxymethylcyclopropane on Oxygen-covered Mo(110): A Radical Clock on a Surface." *J. Am. Chem. Soc***. 2000**, *122*, 12395-12396**.**

  
**1999**

118\. J. D. Batteas, T. S. Rufael, and C. M. Friend, “Influence of Surface Modifiers on the Thermal Decomposition of Methanethiol on Fe(110).” *Langmuir* **1999**, *15*, 2391-2397.  
  
117\. M. Chen, C. M. Friend, and R. A. van Santen, “The Adsorption of Methyl on Rh10 Clusters: Selective C-H Bond Weakening.” *Catalysis Today* **1999,** *50*, 621-627**.**  
  
116\. M. Chen, P. G. Clark, Jr., T. Mueller, C. M. Friend, and E. Kaxiras, “Resolving Discrepancies Between LEED and STM Through *ab-initio* Calculations: Surface and Bonding of Sulfur on Mo(110).” *Phys. Rev. B***. 1999,** *60,* 11783-11788**.**  
  
115\. P. G. Clark, Jr. and C. M. Friend, “Interface Effects on the Growth of Cobalt Nanostructures on Molybdenum-based Substrates." *J. Chem. Phys***. 1999**, *111*, 6991- 6996**.**  
  
114\. C.M. Friend, K.T. Queeney, D.A. Chen, “Structure and Reactivity of Thin Film Oxides and Metals.” **1999**, Applied Surf. Sci., 142 (1-4), 99-105.

  
**1998**

113\. K. T. Queeney and C. M. Friend, “The Role of Oxygen Vacancies in Methanol Reaction on Oxidized Mo(110).” *J. Phys. Chem*. B, **1998**, *102*, 5178-5181.  
  
112\. D. A. Chen and C. M. Friend, “Changing Reactivity of a Bimetallic Surface via Oxidation: Reactions of Methanol on Oxygen-Covered Co Thin Films.” *J. Phys. Chem. B* **1998**, *102*, 106-110.  
  
111\. D. A. Chen and C. M. Friend, “Modifying Selectivity of Thin Films by Intervening Nonmetallic Layers: Reactions of Ethanol-d6 on Supported Co Films." *Surf. Sci***. 1998**, *412-413*, 364-373.  
  
110\. D. A. Chen and C. M. Friend, “Controlling Deoxygenation Selectivity by Surface Modification: Reactions of Ethanol on Oxygen- and Sulfur-Covered Mo(110)." *J. Am. Chem. Soc***. 1998**, *120*, 5017-5023.  
  
109\. D. A. Chen, C. M. Friend, and X. Xu, “Desulfurization of Benzenethiol on Co-Mo(110) Phases." *Surf. Sci***. 1998**, *395*, L221-226.  
  
108\. A. W. Holbert, J. D. Batteas, A. Wong-Foy, T. S. Rufael, and C. M. Friend, “Passivation of Fe(110) via Phosphorous Deposition: The Reactions of Trimethylphosphite." *Surf. Sci***. 1998**, *401*, L437-443**.**  
  
107\. K. T. Queeney and C. M. Friend, “Comment on ‘Methanol on O/Mo(110): Specific Site for Methyl Radical Formation’ by S. C. Street, G. Lui and D.W. Goodman \[Surf. Sci. 385 (1997) L971\]." *Surf. Sci***. 1998**, *407*, 293-295**.**  
  
106\. M. Chen, U. V. Waghmare, C. M. Friend, and E. Kaxiras, “A Density Functional Study of Clean and Hydrogen-covered α-MoO3(010): Electronic Structure and Surface Relaxation." *J. Chem. Phys***. 1998**, *109*, 6854-6860**.**  
  
105\. K. T. Queeney and C. M. Friend, “Competing Pathways for Methoxy Decomposition on Oxygen-covered Mo(110)." *J. Chem. Phys***. 1998**, *109*, 6067-6074**.**  
  
104\. K. T. Queeney, S. Pang, and C. M. Friend, “Spectroscopic Evidence for Perturbed NO Dimers on Oxidized Mo(110)." *J. Chem. Phys***. 1998**, *109*, 8058-8061.  
  
103\. K. T. Queeney and C. M. Friend, “Conversion of Nitrosyls to Dinitrosyls During NO Adsorption on Oxygen-modified Mo(110)." *Surf. Sci***. 1998**, *414*, L957-L963**.**  
  
102\. K. T. Queeney and C. M. Friend, “Stabilization of Nitrosyls by Surface Oxygen: Structure and Reactivity of NO on Oxygen-Modified Mo(110).” *J. Phys. Chem. B,* **1998**, *102*, 9251-9257.  
  
101\. K. T. Queeney, C. R. Arumainayagam, A. Balaji, and C.M. Friend, “Carbon-Carbon Coupling from Formaldehyde Reaction on Mo(110)." *Surf. Sci***. 1998**, *418*, L31-L38.  
  
100\. D. A. Chen and C. M. Friend, “Selective and Nonselective Dehydrogenation in Primary Alcohols: Reactions of Ethanol and 1-Propanol on Co-covered Mo(110).” *Langmuir* **1998**, *14*, 1451-1457.

  
**1997**

99\. C. W. J. Bol, J. D. Kovacs, M. Chen, and C. M. Friend, “Control of Reaction Selectivity via Surface Oxygen Coverage: Thermal Decomposition of Azomethane on Rh(111).” *J. Phys. Chem***. 1997**, *101*, 6436-6442**.**  
  
98\. K. T. Queeney, D. A. Chen, and C. M. Friend, “Probing the Role of Oxygen Coordination in Hydrocarbon Oxidation: Methyl Radical Addition to Oxygen on Mo(110)." *J. Am. Chem. Soc***. 1997**, *119*, 6945-6946.  
  
97\. D. A. Chen and C. M. Friend, “Adsorbate-Induced Structural Changes of Metal Thin Films: Cobalt-Oxygen and Cobalt-Sulfur Overlayers on Mo(110)." *Surf. Sci***. 1997**, *371*, 131-142**.**  
  
96\. C. M. Friend and D. A. Chen, “Fundamental Studies of Hydrodesulfurization by Metal Surfaces.” *Polyhedron* **1997**, *16,* 3165-3175.  
  
95\. M. Chen, S. P. Bates, R. A. Van Santen, and C. M. Friend, “The Chemical Nature of Atomic Oxygen Adsorbed on Rh(111) and Pt(111): A Density Functional Study.” *J. Phys. Chem***. 1997**, *101*, 10051-10057.  
  
94\. D. Chen and C. M. Friend, “Competition between C-O Bond Scission and Retention in Methanol Reaction on Co-covered Mo(110).” *J. Phys. Chem***. 1997**, *101*, 5712-5716.  
  
93\. T. S. Rufael, J. D. Batteas, and C. M. Friend, “The Influence of Surface Oxidation on the Reactions of Methanol on Fe(110).” *Surf. Sci***. 1997**, *384*, 156-167.  
  
92\. K. T. Queeney and C. M. Friend, “Dinitrosyl Intermediate for N2O Formation from Reaction of NO on Mo(110)." *J. Chem. Phys***. 1997**, *107*, 6432-6442.

  
**1996**

91\. M. K. Weldon, P. Uvdal, C. M. Friend, and B. C. Wiegand, “Effect of Surface Modification on the Structure and Reactivity of Cyclohexane on Mo(110)." *Surf. Sci***. 1996**, *355*, 71-84.  
  
90\. M. E. Napier and C. M. Friend, “The Effect of Fluorination on Thiol Reactivity: Reaction of 4,4,4-Trifluorobutanethiol on Mo(110).” *Langmuir* **1996,** *12,* 1800-1807.  
  
89\. B. C. Wiegand, M. E. Napier, C. M. Friend, and P. Uvdal, “Ion and Radical Rearrangements as a Probe of the Mechanism of a Surface Reaction: The Desulfurization of Cyclopropylmethanethiol and 3-Butene-1-thiol on Mo(110)." *J. Am. Chem. Soc***. 1996**, *118*, 2962-2968.  
  
88\. D. A. Chen, C. M. Friend, and H. Xu, “Reactions of Methanethiol on Cobalt-Covered Mo(110).” *Langmuir* **1996**, *12*, 1528-1534.  
  
87\. B. C. Wiegand, C. M. Friend, P. Uvdal, and M. E. Napier, “Facile Homolytic C-S Bond Breaking: The Reaction of 2-Propene-1-thiol on Mo(110).” *Surf. Sci. Lett.* **1996,** *355,* L311-L318.  
  
86\. M. K. Weldon and C. M. Friend, “Probing Surface Reaction Mechanisms Using Chemical and Vibrational Methods: Alkyl Oxidation and Reactivity of Alcohols on Transition Metal Surfaces.” *Chem. Rev*. **1996***, 96*, 1391-1441.  
  
85\. P. Uvdal, M. K. Weldon and C. M. Friend, “Surface-induced Bond Anharmonicity Probed through a Two-Phonon Bound State: Methoxide Adsorbed on Mo(110).” *Phys. Rev. B* **1996**, *53*, 5007-5010.  
  
84\. K. T. Queeney, C. R. Arumainayagam, M. K. Weldon, C. M. Friend, and M. Q. Blumberg, “Differential Reactivity and Structure of Mono- and Dialkoxides: The Reactions of Ethylene Glycol on Mo(110)." *J. Am. Chem. Soc***. 1996**, *118*, 3896-3904.  
  
83\. C. W. J. Bol and C. M. Friend, “Control of Oxidation Selectivity by Alkyl Substitution: The Reactions of t-Butyl Iodide and t-Butanethiol on Rh(111)-p(2x1)-O.” *Surf. Sci. Lett.* **1996***, 364*, L549-L554.  
  
82\. C. W. J. Bol, X. Xu, and C. M. Friend, “Role of Intermolecular Interactions in Determining Structure and Reactivity on Surfaces: Benzenethiol on Rh(111).” *Langmuir* **1996**, *12*, 6083-6090**.**  
  
81\. D. A. Chen and C. M. Friend, “Alcohol Chemistry as a Probe of Mixed Metal Phases: Reactions of 2-Propanol on Cobalt-covered Mo(110).” *J. Phys. Chem***. 1996**, *100*, 17640-17647**.**

  
**1995**

80\. C. W. J. Bol and C. M. Friend, "Selective Oxygen Addition with Sulfur Removal: The Reactions of 2-Propanethiol on Rh(111)-p(2x1)-O." *Surf. Sci..* **1995**, *322,* L271-L274**.**   
  
79\. P. Uvdal, A. D. MacKerell Jr., B. C. Wiegand, and C. M. Friend, “Surface-Induced Alteration of Adsorbate Electronic Structure and Intramolecular Vibrational Coupling: The Vibrational Spectrum of 2-Propoxide on Mo(110).” *Phys. Rev. B* **1995**, *51*, 7844-7848.  
  
78\. M. E. Napier and C. M. Friend, “Effect of Fluorination on Thiol Reactivity: Reaction of 2,2,2-Trifluoroethanethiol on Mo(110).” *J. Phys. Chem***. 1995**, *99*, 8750-8757.  
  
77\. C. W. J. Bol and C. M. Friend, “The Effects of Oxygen on Selectivity: The Reactions of 2-Propyl Thiolate on Oxygen-Covered Rh(111)." *J. Am. Chem. Soc***. 1995**, *117*, 5351-5358.  
  
76\. C. W. J. Bol and C. M. Friend, “Partial Oxidation of C1-Hydrocarbons on Oxygen-covered Rh(111): Formaldehyde from Methylene.” *Surf. Sci.* **1995,** *337*, L800-L806.  
  
75\. M. J. Calhorda, P. E. M. Lopes, and C. M. Friend, “Theoretical Studies of Ethylene Adsorption and Oxidation on Clean and Oxygen Covered Rhodium(111).” *J. Molec. Catal.* **1995***, 97*, 157-172**.**  
  
74\. C. W. J. Bol and C. M. Friend, “Controlling Selectivity in Alkyl Oxidation with Oxygen Coverage: The Reactions of Ethyl and 2-Propyl Iodide on Oxygen-Covered Rh(111).” *J. Phys. Chem***. 1995**, *99*, 11930-11936.  
  
73\. M. K. Weldon and C. M. Friend, “A Novel Method for Product Identification in Complex Surface Reactions using Infrared Absorption Spectroscopy.” *Rev. Sci. Instr.* **1995***, 66*, 5192-5195**.**  
  
72\. C. W. J. Bol and C. M. Friend, “C-O Bond Formation by Direct Addition of Methyl Radicals to Surface Oxygen on Rh(111)." *J. Am. Chem. Soc***. 1995**, *117*, 8053-8054.  
  
71\. M. K. Weldon, P. Uvdal, C. M. Friend, and J. G. Serafin, “Decoupling of Vibrational Modes as a Structural Tool: Coverage-Induced Reorientation of Methoxide on Mo(110)." *J. Chem. Phys***. 1995**, *103*, 5075-5084**.**  
  
70\. C. W. J. Bol and C. M. Friend, “Effects of Oxygen Coverage on the Partial Oxidation of Methylene: Reactions of Diiodomethane on Oxygen-Covered Rh(111)." *J. Am. Chem. Soc***. 1995**, *117*, 11572-11579.

  
**1994**

69\. M. K. Weldon and C. M. Friend, "The Isomerization and Tautomerization of Azomethane on Mo(110)." *Surf. Sci***. 1994**, *310*, 95-102**.**  
  
68\. M. K. Weldon, M. E. Napier, B. C. Wiegand, C. M. Friend, and P. Uvdal, "The Role of Disulfide Linkages in Desulfurization Chemistry: The Reactions of Benzenethiol on a Sulfur-Covered Mo(110) Surface." *J. Am. Chem. Soc***. 1994**, *116*, 8328-8334.  
  
67\. H. Yang, J. L. Whitten, and C. M. Friend, “Adsorption of CH3O on Ni(111)." *Surf. Sci***. 1994**, *313*, 295-307.  
  
66\. P. Uvdal, M. K. Weldon, and C. M. Friend, “Adsorbate Symmetry and Fermi Resonances of Methoxide Adsorbed on Mo(110) as Studied by Surface Infrared Spectroscopy.” *Phys. Rev. B* **1994**, *50*, 12258-12261.  
  
65\. M. K. Weldon and C. M. Friend, “Spectroscopic Characterization of Surface Methylene on Mo(110)." *Surf. Sci***. 1994**, *321*, L202-L208.

  
**1993**

64\. H. Xu and C. M. Friend, "Effect of Sulfur on Desulfurization Kinetics and Selectivity: 2,5-Dihydrothiophene on Mo(110)-(4x1)-S." *J. Phys. Chem***. 1993**, *97*, 3584-3590**.**  
  
63\. H. Xu, P. Uvdal, C. M. Friend, and J. Stöhr, "The Adsorption of 2,5-Dihydro-thiophene on Mo(110)-p(4x1)-S: Ring Orientation as Determined by NEXAFS." *Surf. Sci.* **1993**, *289,* L599-L603**.**

  
**1992**

62\. X. Xu and C. M. Friend, "Selective β-Elimination in the Reaction of 2-Propanol to Acetone on Rh(111)-p(2x1)-O." *Surf. Sci***. 1992**, *260*, 14-22.  
  
61\. X. Xu and C. M. Friend, "Enhanced Kinetic Stability of γ-C-H Bonds in Surface Alkoxides: The Reactions of *tert*-Butyl Alcohol on Clean and Oxygen-Covered Rh(111)." *Langmuir* **1992**, *8*, 1103-1111.  
  
60\. B. C. Wiegand, P. Uvdal, and C. M. Friend, "Probing the Kinetics for Thiol Desulfurization: The Reactions of 2-Methyl-propanethiol on Mo(110)." *J. Phys. Chem***. 1992**, *96*, 4527-4533.  
  
59\. P. Uvdal, B. C. Wiegand, J. G. Serafin and C. M. Friend, "Isotopic Labeling as a Tool to Establish Intramolecular Vibrational Coupling: The Reaction of 2-Propanol on Mo(110)." *J. Chem. Phys***. 1992**, *97*, 8727-8735**.**  
  
58\. B. C. Wiegand and C. M. Friend, "Model Studies of Desulfurization Reactions on Metal Surfaces and in Organometallic Complexes.” *Chem. Rev***. 1992**, *92*, 491-504.  
  
57\. B. C. Wiegand, P. Uvdal, and C. M. Friend, "The Local Structure of Adsorbed Methyl Thiolate: The Reactions of Methanethiol on Mo(110)." *Surf. Sci***. 1992**, *279*, 105-112**.**  
  
56\. B. C. Wiegand, P. Uvdal, J. G. Serafin and C. M. Friend, "Competition between C-O and 1-C-H Bond Scission during Deoxygenation: The Reactions of 1-Propanol on Mo(110)." *J. Phys. Chem***. 1992**, *96*, 5063-5069.

  
**1991**

55\. A. C. Liu and C. M. Friend, "Evidence for Facile and Selective Desulfurization: The Reactions of 2,5-Dihydrothiophene on Mo(110)." *J. Am. Chem. Soc***. 1991**, *113*, 820-826.  
  
54\. X. Xu and C. M. Friend, "Partial Oxidation without Allylic C-H Bond Activation: The Conversion of Propene to Acetone on Rh(111)-p(2x2)-O." *J. Am. Chem. Soc***. 1991**, *113*, 6779-85.  
  
53\. C. M. Friend and X. Xu, "Reactions on Transition Metal Surfaces." *Ann. Rev. Phys. Chem***. 1991**, *42*, 251-278.  
  
52\. B. C. Wiegand, P. E. Uvdal, J. G. Serafin, and C. M. Friend, "Selective α-C-H Bond Cleavage in Alkoxides: 2-Propanol on Mo(110)." *J. Am. Chem. Soc***. 1991**, *113*, 6686-6687.  
  
51\. X. Xu and C. M. Friend, "Partial Oxidation of Olefins: Conversion of Isobutene to *tert*-Butyl Alcohol on Oxygen-Covered Rh(111)." *J. Phys. Chem***. 1991**, *95*, 10753-10759.  
  
50\. X. Xu and C. M. Friend, "The Effect of Rhodium Environment on Oxidation Mechanism: Conversion of Norbornene to Norbornanone on Rh(111)-p(2x1)-O." *J. Am. Chem. Soc***. 1991**, *113*, 8572-8573.  
  
49\. F. A. Flitsch, J. R. Swanson, and C. M. Friend, "Thermal and Photoinduced Decomposition of W(CO)6 on W(110)." *Surf. Sci***. 1991**, *245*, 85-95.

  
**1990**

48\. M. Calhorda, R. Hoffmann, and C. M. Friend, "Adsorption and Reactions of Cyclic Sulfides on Mo(110)." *J. Am. Chem. Soc***. 1990**, *112*, 50-61.  
  
47\. J. R. Swanson, F. A. Flitsch, and C. M. Friend, "Evidence for Photochemical Quenching by a Surface: Laser Induced Decomposition of W(CO)6 on Si(111)-(7x7)." *Surf. Sci***. 1990**, *226*, 147-168.  
  
46\. A. C. Liu, C. M. Friend, and J. Stöhr, “The Orientation of Phenoxide on Oxygen-precovered Mo(110)." *Surf. Sci***. 1990**, *236*, L349-L352**.**  
  
45\. A. C. Liu, J. Stöhr, C. M. Friend, and R. J. Madix, “A Critical Interpretation of the Near edge X-Ray Absorption Fine Structure of Chemisorbed Benzene." *Surf. Sci***. 1990**, *235*, 107-115**.**  
  
44\. X. Xu and C. M. Friend, “Selective Oxidation Reactions on Rh(111)-p(2x2)-O: The Conversion of Styrene to Acetophenone." *J. Am. Chem. Soc***. 1990**, *112*, 4571-4573.

  
**1989**

43\. J. G. Serafin and C. M. Friend, "Reactivity of Pyridine on Mo(110): C-H and C-N Bond Activation." *J. Phys. Chem***. 1989**, *93*, 1998-2004.  
  
42\. J. G. Serafin and C. M. Friend, "Carbon-Oxygen Bond Strength as a Control of Reaction Kinetics: Phenol on Mo(110)." *Surf. Sci***. 1989**, *209*, L163-L175.  
  
41\. J. R. Swanson, F. A. Flitsch, and C. M. Friend, "Low Energy Electron Induced Decomposition on Surfaces: W(CO)6 on Si(111)-(7x7)." *Surf. Sci***. 1989**, *215*, L293-L296.  
  
40\. J. G. Serafin and C. M. Friend, "Inhibition of C-H and C-O Bond Activation by Surface Oxygen: Stabilization of Phenoxide in the Reaction of Phenol on Oxygen Precovered Mo(110)." *J. Am. Chem. Soc***. 1989**, *111*, 4233-4239.  
  
39\. A. C. Liu and C. M. Friend, "Alkane Activation: The Adsorption and Reaction of Ethane on W(100)." *Surf. Sci***. 1989**, *216*, 33-48.  
  
38\. J. G. Serafin and C. M. Friend, "Controlling Factors in Deoxygenation Kinetics and Selectivity: The Reactions of Ethylene Oxide on Mo(110)." *J. Am. Chem. Soc***. 1989**, *111*, 6019-6026.  
  
37\. X. Xu and C. M. Friend, "The Role of Coverage in Determining Adsorbate Stability: Phenol Reactivity on Rh(111)." *J. Phys. Chem***. 1989**, *93*, 8072-8080.  
  
36\. B. C. Wiegand, C. M. Friend, and J.T. Roberts, "Adsorbate Thermodynamics as a Determinant of Reaction Mechanism: Pentamethylene Sulfide on Mo(110)." *Langmuir* **1989**, *5*, 1292-1298.  
  
35\. J. G. Serafin and C. M. Friend, "Evidence for Formation of Gaseous Methyl Radicals in the Decomposition of Methoxide on Oxygen-Precovered Mo(110)." *J. Am. Chem. Soc***. 1989**, *111*, 8967-8969.

  
**1988**

34\. C. M. Friend and J. G. Serafin, "Bonding and Reactivity of Acetonitrile on W(100)-(5x1)-C." *J. Chem. Phys*., **1988**, *88*, 4037-4045.  
  
33\. J. T. Roberts and C. M. Friend, "Vibrational Studies of 1-Propanethiol on Mo(110): Spectroscopic Evidence for Low Temperature Thiolate Formation." *Surf. Sci***. 1988**, *198*, L321-L328.  
  
32\. J. T. Roberts and C. M. Friend, "Desulfurization of Ethylene Sulfide on Mo(110): The Roles of Ring Size and Strain in Adsorbate Reaction Selectivity." *Surf. Sci***. 1988**, *202*, 405-432.  
  
31\. J. T. Roberts and C. M. Friend, "Spectroscopic Identification of Surface Phenyl Thiolate and Benzyne on Mo(110)." *J. Chem. Phys***. 1988**, *88*, 7172-7180.  
  
30\. J. T. Roberts and C. M. Friend, "Reactions of Ethanethiol on Mo(110): Formation and Decomposition of a Surface Alkyl Thiolate." *J. Phys. Chem***. 1988**, *92*, 5205-5213.  
  
29\. J. G. Serafin and C. M. Friend, "Evidence for Nitrile Hydrogenation on W(100)-(5x1)-C: Spectroscopic Studies of Surface Intermediates Derived from HCN." *J. Phys. Chem***. 1988**, *92*, 6694-6700.  
  
28\. C. M. Friend and J. T. Roberts, "Deduction of Reaction Mechanisms for Surface Processes: Desulfurization of Organic Sulfides and Thiols on Mo(110)." *Accts. Chem. Res.* **1988***, 21*, 394-400.  
  
27\. P. A. Stevens, R. J. Madix, and C. M. Friend, "Adsorbate Structural Determination of CO and HCNH Using C-K Edge NEXAFS on W(100)-(5x1)-C." *Surf. Sci***. 1988**, *205*, 187-206.  
  
26\. A. C. Liu and C. M. Friend, "The Structure and Reactivity of Chemisorbed Aromatics: Spectroscopic Studies of Benzene on Mo(110)." *J. Chem. Phys***. 1988**, *89*, 4396-4405.

  
**1987**

25\. J. R. Swanson, C. M. Friend, and Y. J. Chabal, "Laser-assisted Deposition of Iron on Si(111)-(7x7): The Mechanism and Energetics of Fe(CO)5 Decomposition." *J. Chem. Phys***. 1987**, *87*, 5028-5037. \[Erratum *J. Chem. Phys***. 1988**, *89*, 2593.\]  
  
24\. J. T. Roberts and C. M. Friend, "The Reactions of Thiophene on Mo(110) and Mo(110)-p(2x2)-S." *Surf. Sci***. 1987**, *186*, 201-218.  
  
23\. J. T. Roberts and C. M. Friend, "Coadsorption as a Probe of Mechanism: Cyclic Sulfides and Straight Chain Thiols on Mo(110)." *J. Am. Chem. Soc***. 1987**, *109*, 4423-4424.  
  
22\. C. M. Friend, J. G. Serafin, E. K. Baldwin, P. A. Stevens, and R. J. Madix, "Bonding and Adsorption Structure of CO on W(100)-(5x1)-C." *J. Chem. Phys***. 1987**, *87*, 1847-1850.  
  
21\. E. K. Baldwin and C. M. Friend, "Alteration in Dissociation Energetics for π-Acceptor Adsorbates: N2O, NO, N2 and O2 on W(100)-p(5x1)-C." *J. Phys. Chem*., **1987**, *91*, 3821-3827.  
  
20\. A. C. Liu and C. M. Friend, "Alkane Activation: Adsorption and Reaction of *n*-Butane on Clean and Carbided W(100)." *J. Chem. Phys*., **1987**, *87*, 4975-4985.  
  
19\. J. T. Roberts and C. M. Friend, "Ring Size and Strain as a Control of Reaction Selectivity: Ethylene Sulfide on Mo(110)." *J. Am. Chem. Soc***. 1987**, *109*, 7899-7900.  
  
18\. J. T. Roberts and C. M. Friend, "Desulfurization of Saturated C3S Molecules on Mo(110): The Effect of Ring Strain." *J. Am. Chem. Soc***. 1987**, *108*, 3872-3882.

  
**1986**

17\. K. A. Pearlstine and C. M. Friend, "Alteration in Surface Reaction Selectivity of Nitriles. 1. HCN on W(100) and W(100)-(5x1)-C." *J. Phys. Chem***. 1986**, *90*, 4341-4343.  
  
16\. K. A. Pearlstine and C. M. Friend, "Alteration in Surface Reaction Selectivity of Nitriles. 2. CH3CN on W(100) and W(100)-(5x1)-C." *J. Phys. Chem***. 1986**, *90*, 4344-4347.  
  
15\. A. C. Liu and C. M. Friend, "Computer-controlled Mass Spectral Search for Reaction Products in a Thermal Desorption Experiment." *Rev. Sci. Instrum***. 1986**, *57(8),* 1519-1522.  
  
14\. K. A. Pearlstine and C. M. Friend, "Surface Chemistry of Alkyl Amines. 1. Ethylamine and Triethylamine on W(100), W(100)-(5x1)-C, and W(100)-(2x1)-O." *J. Am. Chem. Soc***. 1986**, *108*, 5837-5842.  
  
13\. K. A. Pearlstine and C. M. Friend, "Surface Chemistry of Alkyl Amines. 2. Methylamine and Trimethylamine on W(100), W(100)-(5x1)-C and W(100)-(2x1)-O." *J. Am. Chem. Soc***. 1986**, *108*, 5842-5847.  
  
12\. J. T. Roberts and C. M. Friend, "Model Hydrodesulfurization Reactions: Saturated C4S Molecules on Mo(110)." *J. Am. Chem. Soc***. 1986**, *108*, 7204-7210.

  
**1985**

11\. E. K. Baldwin and C. M. Friend, “Reaction of NO on W(100), W(100)-p(2x2)-O, and W(100)-p(2x1)-O Surfaces: A Nondissociative Pathway for N-N Bond Formation.” *J. Phys. Chem***. 1985**, *89*, 2576-2581**.**  
  
10\. K. A. Pearlstine and C. M. Friend, "C-C Bond Activation: Cycloheptatriene Reaction on W(100), W(100)-(5x1)-C, and W(100)-(2x1)-O." *J. Am. Chem. Soc***. 1985**, *107*, 5898-5901.

  
**1983**

9\. D. A. Outka, C. M. Friend, S. Jorgensen, and R. J. Madix, "Adsorption and Hydrogenation of Acetylene on Cu(110) and Cu(110)-O Surfaces.” *J. Am. Chem. Soc***. 1983**, *105*, 3468-3472.  
  
8\. D. A. Outka, S. W. Jorgensen, C. M. Friend, and R. J. Madix, "Adsorption and Reaction of Cyanogen on Clean and Oxygen-Dosed Cu(110) Surfaces.” *J. Molec. Catal***. 1983**, *21*, 375-387.

  
**1982**

7\. R. M. Wexler, M.-C. Tsai, C. M. Friend, and E. L. Muetterties, "Pyridine Coordination Chemistry of Nickel and Platinum Surfaces." *J. Am. Chem. Soc***. 1982**, *104*, 2034-2038.  
  
6\. M.-C. Tsai, C. M. Friend, and E. L. Muetterties, "Dehydrogenation Processes on Nickel and Platinum Surfaces. Conversion of Cyclohexane, Cyclohexene, and Cyclohexadiene to Benzene." *J. Am. Chem. Soc***. 1982**, *104*, 2539-2543.  
  
5\. M.-C. Tsai, J. Stein, C. M. Friend, and E. L. Muetterties, "Chemistry of Cyclic Olefins and Polyenes on Nickel and Platinum Surfaces.” *J. Am. Chem. Soc***. 1982**, *104*, 3533-3534.

  
**1981**

4\. C. M. Friend, J. Stein, and E. L. Muetterties, "Coordination Chemistry of Metal Surfaces. 2. Chemistry of CH3CN and CH3NC on Nickel Surfaces." *J. Am. Chem. Soc***. 1981**, *103*, 767-772.  
  
3\. C. M. Friend and E. L. Muetterties, "Coordination Chemistry of Metal Surfaces. Benzene and Toluene Interactions with Nickel Surfaces." *J. Am. Chem. Soc***. 1981**, *103*, 773-779.  
  
2\. C. M. Friend, E. L. Muetterties, and J. L. Gland, "Vibrational Studies of CH3CN and CH3NC Adsorbed on Ni(111) and Ni(111)-C Surfaces." *J. Phys. Chem***. 1981**, *85*, 3256-3262.

  
**1980**

1\. C. M. Friend, R. M. Gavin, E. L. Muetterties, and M.-C. Tsai, "Coordination Chemistry of Metal Surfaces - Carbon Monoxide Chemisorption States on Pt(111)." *J. Am. Chem. Soc***. 1980**, *102*, 1717-1719.